Yeah, it used to be the case that leaving water to sit overnight was not only for bringing it up to room temperature but also for allowing the chlorine in tap water to evaporate out. These days most tap water also contains chloramines (which can't be removed by just sitting) and trace heavy metals - so water conditioners/dechlorinators are routinely used anyway - so yes from that point of view it's not as necessary. I guess it depends on how much water you need and whether you are going to be adding it at room temperature or heating it up to tank temperature before adding anyway. Also, personal preference too, some people just prefer to let tap water "age" before use - so if you have the space for that then that's fine too