In a healthy cycled tank, ammonia and nitrite should be 0, nitrate should be anywhere up to 20 ad the pH should remain consistently steady at any point between 6.8 and 8.5. GH and KH are measurements of water hardness; if they are over 100 then your water is hard enough to stop the pH swinging.
So, your test shows that ammonia and nitrite are a slight problem (is your tank still cycling for some reason?), nitrate is a real problem - you need to do some large water changes to get that down to 40 or lower - and your pH, GH and KH are all fine.

It's usual to test before you do cleaning and water changes; that gives you a more accurate picture of what the conditions are actually like in the tank.
HTH.